1. Institute for Geosciences; Johannes Gutenberg-University Mainz; J.-J.-Becher-Weg 21 55128 Mainz Germany
2. Climate Geochemistry Department; Max Planck Institute for Chemistry (Otto-Hahn-Institute); P.O. Box 3060 55020 Mainz Germany
3. Department of Chemical and Geological Sciences; University of Modena and Reggio Emilia; Via Campi 103 41125 Modena Italy
4. Lamont-Doherty Earth Observatory; Columbia University; Palisades NY 10964 USA