LAYER-BY-LAYER SELF-ASSEMBLY APPROACH IN THE UV PROTECTIVE MODIFICATION OF ARAMID-BASED MATERIALS

Author:

ÜNVAR Yeşim1,SARIIŞIK Merih1,UĞUR Şule Sultan2

Affiliation:

1. DOKUZ EYLÜL ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ, TEKSTİL MÜHENDİSLİĞİ BÖLÜMÜ, TEKSTİL MÜHENDİSLİĞİ PR.

2. SÜLEYMAN DEMİREL ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ, TEKSTİL MÜHENDİSLİĞİ BÖLÜMÜ, TEKSTİL MÜHENDİSLİĞİ PR.

Abstract

This paper presents the Layer by Layer self-assembly (LbL) approach for developing the UV resistance of aramid yarns. Initially, a pretreatment was achieved by polyethyleneimine to obtain cationic surface charges on aramid yarns. Then zinc oxide and titanium dioxide nanoparticles were self-assembled on these yarns by the LbL process. The findings revealed that the LbL nano coatings significantly improved the UV resistance and tensile properties of the aramid yarns. This study highlights the unique opportunities offered by the LbL methodology to both modify aramid-based materials in mild conditions and provide an effective UV protection.

Publisher

UCTEA Chamber of Textile Engineers

Subject

Industrial and Manufacturing Engineering,General Materials Science

Reference6 articles.

1. 1. Zhu, X., Yuan, L., Liang, G., & Gu, A., (2014), Unique UV-resistant and surface active aramid fibers with simultaneously enhanced mechanical and thermal properties by chemically coating Ce 0.8 Ca 0.2 O 1.8 having low photocatalytic activity, Journal of Materials Chemistry A, 2(29), 11286-11298.

2. 2. Zhang, H., Liang, G., Gu, A., & Yuan, L., (2014), Facile preparation of hyperbranched polysiloxane-grafted aramid fibers with simultaneously improved UV resistance, surface activity, and thermal and mechanical properties, Industrial & Engineering Chemistry Research, 53(7), 2684-2696.

3. 3. Zhu, X., Yuan, L., Liang, G., & Gu, A., (2015), Unique surface modified aramid fibers with improved flame retardancy, tensile properties, surface activity and UV-resistance through in situ formation of hyperbranched polysiloxane–Ce 0.8 Ca 0.2 O 1.8 hybrids, Journal of Materials Chemistry A, 3(23), 12515-12529.

4. 4. Zhou, L., Yuan, L., Guan, Q., Gu, A., & Liang, G., (2017), Building unique surface structure on aramid fibers through a green layer-by-layer self-assembly technique to develop new high performance fibers with greatly improved surface activity, thermal resistance, mechanical properties and UV resistance, Applied Surface Science, 411, 34-45.

5. 5. Zhu, J., Yuan, L., Guan, Q., Liang, G., & Gu, A., (2017), A novel strategy of fabricating high performance UV-resistant aramid fibers with simultaneously improved surface activity, thermal and mechanical properties through building polydopamine and graphene oxide bi-layer coatings, Chemical Engineering Journal, 310, 134-147.

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