The γ-radiolysis of cyclohexane with electron scavengers. V. C6F12 as an electron scavenger in the vapor phase

Author:

Sagert N. H.,Blair A. S.

Abstract

The radiolysis of cyclohexane in the vapor phase has been examined in the presence of up to 3 mole % perfluorocyclohexane. The results indicate that perfluorocyclohexyl radicals are produced with a yield of 2.0 G units at 3% perfluorocyclohexane. It is concluded that these radicals are formed when the perfluorocyclohexyl anions are neutralized. The relevance of this neutralization to the liquid phase radiolysis of cyclohexane is discussed.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 11 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Reduction of Polyfluorinated Compounds;The Journal of Physical Chemistry B;2003-09-09

2. Pulse- and gamma ray-radiolysis of cyclohexane: Ion recombination mechanisms;Radiation Physics and Chemistry (1977);1983-01

3. Radiolysis of 1,1-difluoroethane;The Journal of Physical Chemistry;1974-10

4. Effect of Pressure in the Gamma Radiolysis of Cyclohexane in the Vapor Phase;Helvetica Chimica Acta;1974-04-27

5. Electron disappearance in pulse irradiated fluorocarbon gases;The Journal of Chemical Physics;1973-08-15

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