Author:
Cazianis C. T.,Eaton D. R.
Abstract
A spin-labelled ligand is defined as a molecule with two functional groups, one of which provides a Lewis base site suitable for complexing to a metal ion. The second functional group comprises a site bearing an unpaired electron. The possible utility of such compounds in coordination chemistry has been explored. The spin density distribution in 4-pyridyl-t-butyl nitroxide provides information on the relative electron accepting abilities of different metal ions in various ligand environments. A method for measuring the rates of very rapid ligand exchange reactions is also suggested.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
25 articles.
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