Author:
Hurni Krysten L,Baines Kim M
Abstract
The photolysis of dimesitylbis(trimethylsilyl)germane (3) in hexanes or THF, at low temperature, has been investigated as a potential method for the preparative-scale synthesis of tetramesityldigermene (5). A product mixture, consisting of hexamethyldisilane, mesitylene, 2-trimethylsilylmesitylene (7), a new germacyclobutene (8), and an unidentified polymer, was obtained. No evidence for the formation of tetramesityldigermene (5) was observed.Key words: diaryldisilylgermane, digermene, germylene, germacyclobutene, photolysis.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
7 articles.
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