La photolyse du sulfure de méthyle et de vinyle

Abstract

The photolysis of methylvinylsulfide in the 230–270 nm region yields products which can be explained by the following primary reactions.[Formula: see text]The methyl and vinyl radicals are titrated by the addition of methyl mercaptan to the system.[Formula: see text]At short photolysis time, the sum of the methane and ethylene quantum yields is near unity.