Studies in the usnic acid series. V. The base catalyzed usnic acid – isousnic acid rearrangement. Part III. (—)-Usnic acid isomethoxide monoacetate

Author:

Kutney James P.,Sanchez Ignacio H.

Abstract

Further studies on the base catalyzed usnic acid – isousnic acid rearrangement process clarify the situation concerning (−)-usnic acid isomethoxide monoacetate (7). This substance is now shown to be a mixture of the two possible C4a epimers. These and previous data allow a mechanism to be proposed for this interesting rearrangement.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 10 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Usnic acid: preparation, structure, properties and chemical transformations;Russian Chemical Reviews;2012-08-31

2. Synthesis of chalcones derived from (+)- and (−)-usnic acids;Russian Chemical Bulletin;2011-11

3. Oxidation of usninic acid;Chemistry of Natural Compounds;2010-11

4. New esters of R-(+)-usnic acid;Il Farmaco;1998-11

5. Recent Progress in the Chemistry of Lichen Substances;Fortschritte der Chemie organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products;1984

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