Abstract
Two compounds, originally formulated by Price as Na2Mn2I2O11 and K2Mn2I2O11 have been shown to be NaMnIO6•1/2H2O and KMnIO6•1/2H2O. Consequently they are compounds of tetravalent manganese, a conclusion confirmed by their magnetic susceptibilities, and by their reactions with a variety of reducing agents; the reactions with ferrous ions, iodide ions, sulphur dioxide, hydroxylamine hydrochloride, and hydrazine hydrochloride were examined. Some of the properties of these compounds are described, and their X-ray powder diagrams show them to be analogous to the nickel salts NaNiIO6•H2O and KNiIO6•1/2H2O.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
17 articles.
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