13C T1 nuclear magnetic resonance study of molecular motion: rotational barriers in hindered methyl groups-Reference-Cited by-同舟云学术

13C T1 nuclear magnetic resonance study of molecular motion: rotational barriers in hindered methyl groups

Published:1976-09-01 Issue:17 Volume:54 Page:2820-2826
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Axelson David E.,Holloway Clive E.

Abstract

Analysis of spin–lattice relaxation (T1) data can give information on restricted rotation which is otherwise inaccessible. This study investigates the influence of substituents on the rotation of a neighbouring methyl group in a series of related polycyclic compounds.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v76-399

Cited by 23 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Comparison of the Woessner and the ‘model-free’ approaches for the analysis of carbon-13 spin-lattice relaxation data for methyl groups;Magnetic Resonance in Chemistry;1992-03

2. Rotation barriers of interacting axial methyl groups;The Journal of Physical Chemistry;1986-08

3. Measurement of methyl rotation barriers by NMR spectroscopy;The Journal of Physical Chemistry;1986-03

4. Intramolecular motion and reorientational barriers in 9-fluorenone, 4-methyl-9-fluorenone and 4,5-dimethyl-9-fluorenone;Magnetic Resonance in Chemistry;1985-01

5. The influence of molecular geometries and experimental errors on rotational diffusion constants, methyl jumping rates, and activation parameters as calculated from 13C relaxation data;Journal of Magnetic Resonance (1969);1984-10