Rational size control of gold nanoparticles employing an organometallic precursor [Au-C≡C- t-Bu]4 and tunable thiolate-functionalized ionic liquids in organic medium-Reference-Cited by-同舟云学术

Rational size control of gold nanoparticles employing an organometallic precursor [Au-C≡C- t-Bu]4 and tunable thiolate-functionalized ionic liquids in organic medium

Published:2012-01 Issue:1 Volume:90 Page:145-152
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Luska Kylie L.¹,Moores Audrey¹

Affiliation:

1. Department of Chemistry, McGill University, 801 Sherbrooke St. West, Montreal, QC H3A 2K6, Canada.

Abstract

Gold nanoparticles (Au NPs) stabilized with six different thiolate-functionalized ionic liquids (TFILs) were synthesized in an organic solvent. The size and optical properties of the TFIL-stabilized Au NPs can be rationally controlled by altering the N-alkyl chain length and (or) the counteranion of the TFIL-stabilizing ligand. Au NPs were prepared from the reduction of a gold precursor (HAuCl4 or [Au-C≡C-t-Bu]4) employing NaBH4 in the presence of the different disulfide precursors. A model, based on Israelachvili theory, is proposed to account for the dependence of NP size on the N-alkyl chain length and the counteranion of the surfactantlike TFIL stabilizers.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v11-146

Reference44 articles.

1. The plasmon band in noble metal nanoparticles: an introduction to theory and applications

2. Surface plasmon subwavelength optics

3. Selective oxidation using gold

4. Selective oxidation with dioxygen by gold nanoparticle catalysts derived from 55-atom clusters

5. Structure Sensitivity of Carbon−Nitrogen Ring Opening: Impact of Platinum Particle Size from below 1 to 5 nm upon Pyrrole Hydrogenation Product Selectivity over Monodisperse Platinum Nanoparticles Loaded onto Mesoporous Silica

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