Author:
Wiesner K.,Sanchez I. H.,Atwal K. S.,Lee S. F.
Abstract
Two highly stereoselective syntheses of the methoxy ketal 18, which had been previously transformed to the chasmanine model compound IV are described. Both these processes avoid the equilibration step [Formula: see text] which failed (with compounds [Formula: see text]) in the actual chasmanine synthesis. There is reason to believe that the second of these routes, remarkable by its brevity, will be applicable in the full chasmanine system.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
14 articles.
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