Abstract
Acetolysis of 1,2;5,6-di-O-isopropylidene-α-D-allofuranose occurred with inversion at C-2 in a medium composed of acetic acid, acetic anhydride, and sulfuric acid. D-Altrose was isolated in 45% yield by deacetylation and chromatographic separation of the mixture of products. Unsubstituted D-allose did not epimerize under the same reaction conditions.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
26 articles.
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