The role of solvent in organometallic chemistry — Oxidative addition with dichloromethane or chloroform-Reference-Cited by-同舟云学术

The role of solvent in organometallic chemistry — Oxidative addition with dichloromethane or chloroform

Published:2012-01 Issue:1 Volume:90 Page:46-54
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Abo-Amer Anwar¹,McCready Matthew S.²,Zhang Fenbao²,Puddephatt Richard J.²

Affiliation:

1. Department of Chemistry, Al al-Bayt University, Al-Mafraq, Jordan.

2. Department of Chemistry, The University of Western Ontario, London, ON N6A 5B7, Canada.

Abstract

Dimethylplatinum(II) complexes [PtMe2(NN)], with NN = diimine ligand, can react with dichloromethane or chloroform solvent to give the corresponding organoplatinum(IV) complexes [PtClMe2(CH2Cl)(NN)] or [PtClMe2(CHCl2)(NN)], respectively. The products can exist in isomeric forms, corresponding to products of cis or trans oxidative addition. The structures of three dichloromethane adducts and one chloroform adduct are reported.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v11-096

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