Author:
Chung Henry L.,Tuck Dennis G.
Abstract
Preparative and spectroscopic studies show that the interaction of 2-formylpyrrole, C4H4N. CHO, and 2-acetylpyrrole, C4H4N·COCH3 (= HL), with In(III) may involve the organic base as either a bidentate organic anion ligand to give InL3 complexes, (L = 2-acetylpyrrolate only) or as a neutral monodentate species to form InCl3·3HL. The spectroscopic and kinetic properties of the organometallic derivatives Me2InL are also discussed. The polarographic reduction of InL3 (L = 2-acetylpyrrole anion) involves three one-electron reduction steps.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
9 articles.
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