Abstract
The reaction of benzeneselenenyl thiocyanate with E- and Z-1-phenylpropene has been shown to give products under conditions of kinetic control of net stereospecific syn addition in the Markownikoff orientation. Furthermore, the reactions were highly specific in that a thiocyanato adduct was formed exclusively from the Z-isomer, whereas an isothiocyanato adduct was formed exclusively from the E-isomer.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
25 articles.
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