Reaction of iron carbonyls with amides and thionamides

Author:

Alper Howard,Edward John T.

Abstract

Iron pentacarbonyl in boiling butyl ether converts primary amides or thionamides to nitriles, and benzanilide or thionbenzanilide to N-benzylideneaniline. Diiron nonacarbonyl reacts with p-methoxy-thionbenzamide to form a complex C22H16N2S2O8Fe2; a possible structure is proposed.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 14 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. A Career in Catalysis: Howard Alper;ACS Catalysis;2019-06-11

2. Microwave-assisted synthesis of thioamides with elemental sulfur;Journal of Sulfur Chemistry;2011-12-20

3. Pentacarbonyliron;Encyclopedia of Reagents for Organic Synthesis;2008-03-14

4. Pentacarbonyliron;Encyclopedia of Reagents for Organic Synthesis;2001-04-15

5. Organoiron Compounds in Stoichiometric Organic Synthesis;Comprehensive Organometallic Chemistry;1982

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