Ozonolysis of Acetals. (1) Ester Synthesis, (2) THP Ether Cleavage, (3) Selective Oxidation of β-Glycoside, (4) Oxidative Removal of Benzylidene and Ethylidene Protecting Groups

Author:

Deslongchamps Pierre,Moreau Claude

Abstract

Ozone reacts very smoothly with acetals to give the corresponding esters. Tetrahydropyranyl ethers, β-glycopyranosides, ethylidene, or benzylidene derivatives are also oxidized whereas the α-glycopyranosides are inert.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

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