Author:
MacLean David B.,Prime H. C.
Abstract
The permanganate oxidation product of annotinine is shown to be an amide that contains the ether ring of annotinine still intact. The Clemmensen reduction of this compound to the saturated base, C16H23O2N, was re-examined. A number of intermediates were isolated from the system and these were also prepared from the oxidation product by other methods. Analogous reactions of annotinine chlorohydrin were also studied. From these results suggestions are presented regarding the size of the ether ring and its position relative to the nitrogen atom.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
18 articles.
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