Studies towards the total synthesis of ouabagenin-Reference-Cited by-同舟云学术

Studies towards the total synthesis of ouabagenin

Published:2005-06-01 Issue:6-7 Volume:83 Page:728-740
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Chen Ling,Deslongchamps Pierre

Abstract

An anionic cyclization strategy developed in our laboratory was used to produce a versatile and convergent synthesis of an advanced tetracyclic intermediate for the construction of ouabagenin and closely related analogs.Key words: organic chemistry, synthesis, cycloaddition, polycyclization, Michael reaction, DielsAlder reaction, steroids, oubain, ouabagenin, natural products.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v05-042

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4. Application of intramolecular Heck reactions to the preparation of steroid and terpene intermediates having cis A-B ring fusions. Model studies for the total synthesis of complex cardenolides.

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