Author:
Lalancette J. M.,Beauregard Y.,Bhereur M.
Abstract
The preparation of (CH3S)2AlCH3 and (CH3S)3Al from trimethylaluminum and methanethiol is reported. The reaction of CO2, COS, and CS2 with (CH3S)2AlCH3 yields (CH3S)3C—C(CH3S)3 and thiocarbonates respectively, besides dimethyl disulfide. With the same disubstituted aluminum derivative, phenylacetylene reacted to give C5H5C(SCH3)CH2. A study with deuterated phenylacetylene has permitted us to establish the mechanism of this reaction.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
8 articles.
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