PRODUCTION AND PROPERTIES OF 2,3-BUTANEDIOL: XXIV. THE CYCLIC SULPHITES OF meso- AND levo-2,3-BUTANEDIOL

Author:

Robertson Florence M.,Neish A. C.

Abstract

levo-2,3-Butanediol reacts spontaneously with thionyl chloride to give good yields of its cyclic sulphite (b.p. 177° to 178 °C.). This ester is optically active [Formula: see text] and can be hydrolyzed by dilute hydrochloric acid to pure levo-2,3-butanediol and sulphurous acid. The cyclic sulphite of meso-2,3-butanediol (b.p. 188° to 189 °C.) was also prepared.

Publisher

Canadian Science Publishing

Subject

Pharmacology (medical),Complementary and alternative medicine,Pharmaceutical Science

Reference5 articles.

Cited by 5 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. C2O2S Ring Systems;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02

2. The synthesis and the 1h- and 13c-nuclear magnetic resonance spectroscopy of the cyclic sulfites of some sugars;Carbohydrate Research;1979-11

3. Organic Sulfur Compounds. XI. The Reactions of the Cyclic Sulfites with the Aromatic Aldehydes;Bulletin of the Chemical Society of Japan;1966-08

4. The Present Status of the 2, 3-Butylene Glycol Fermentation;Advances in Applied Microbiology;1963

5. Preparation and Hydrolysis of Some Acetals and Esters of D(—)-2,3-Butanediol;Journal of the American Chemical Society;1950-12

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