Mechanism of dihydride formation and hydrogen/deuterium exchange in a cationic iridium(III) complex-Reference-Cited by-同舟云学术

Mechanism of dihydride formation and hydrogen/deuterium exchange in a cationic iridium(III) complex

Published:2009-10 Issue:10 Volume:87 Page:1362-1368
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Cavallo Luigi¹²³,Nolan Steven P.¹²³,Jacobsen Heiko¹²³

Affiliation:

1. Dipartimento di Chimica, Università di Salerno, Italy.

2. School of Chemistry, University of St. Andrews, St-Andrews, KY16 9ST UK.

3. KemKom, 1215 Ursulines Ave, New Orleans, LA 70116, USA.

Abstract

In this manuscript, we provide a theoretical rationalization of the mechanisms that control double H2 addition to an unsaturated 14 e cationic Ir(III) complex to yield a dihydride Ir(III) complex. Further, we also present two mechanisms that can explain the experimentally observed incorporation of deuterium into the tert-Butyl (tBu) groups of the N-heterocyclic ItBu ligands.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/V09-091

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