Collision-induced microwave absorption in gaseous mixtures of various rare gases at 2.3 cm−1

Abstract

Collision-induced microwave absorption has been observed at 2.3 cm−1 for the rare gas mixtures Ne–Kr, Ar–Kr, Ar–Xe, and Kr–Xe. The absorption coefficient has been measured at room temperature for density products up to 8000 amagat2 and for various density ratios. These results have been used in conjunction with those of the infrared region to determine more accurately the zeroth moment for each of the spectra and hence have allowed improved values for the induced dipole moment parameters for the exponential model. Upper limits to the absorption in He–Xe and He–Ar mixtures in the microwave region have also been established.