Affiliation:
1. Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1W5
Abstract
The weaker electronic transitions in the region 2000–9000 Å in the emission spectrum of GeF have been photographed at high dispersion; three new transitions with the A2Σ+ state as lower state have been discovered, and the various systems near 2100 and 8600 Å have been reassigned. The spectra have been explained in terms of six excited states lying between 40 000 and 50 000 cm−1 above the ground state, and representative bands involving all six have been analyzed rotationally. Five of these excited states are Rydberg states (5pσ, 5pπ, 4dπ, 4dδ, and 6sσ), and the other is the σπ22Δ valence state; this latter interacts strongly with the 4dδ 2Δ state.
Publisher
Canadian Science Publishing
Subject
General Physics and Astronomy
Cited by
19 articles.
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1. Molecular constants of FGe X2Π1/2 fluorogermylidyne;Landolt-Börnstein - Group II Molecules and Radicals;2021
2. Diatomic Silylynes, Germylynes, Stannylynes, and Plumbylynes: Structures, Dipole Moments, Dissociation Energies, and Quartet-Doublet Gaps of EH and EX (E = Si, Ge, Sn, Pb; X = F, Cl, Br, I);Inorganic Chemistry;2013-06-03
3. Cationic Germanium Fluorides: A Theoretical Investigation on the Structure, Stability, and Thermochemistry of GeFn/GeFn+ (n = 1−3);The Journal of Physical Chemistry A;2006-03-16
4. Molecules for Materials: Structures, Thermochemistry, and Electron Affinities of the Digermanium Fluorides Ge2Fn/Ge2Fn- (n=1-6): A Wealth of Unusual Structures;ChemPhysChem;2002-02-15
5. Structures, thermochemistry, and electron affinities of the germanium fluorides, GeFn/GeFn−(n=1–5);The Journal of Chemical Physics;1999-11