The formation and structure of a 1,5-disubstituted S4N4 ring, (Ph3P=N)2S4N4, from the reaction of triphenylphosphine with tetrasulphur tetranitride-Reference-Cited by-同舟云学术

The formation and structure of a 1,5-disubstituted S4N4 ring, (Ph3P=N)2S4N4, from the reaction of triphenylphosphine with tetrasulphur tetranitride

Published:1979-12-01 Issue:23 Volume:57 Page:3171-3172
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Bojes Josef,Chivers Tristram,MacLean Greg,Oakley Richard T.,Cordes A. Wallace

Abstract

Two novel products, (Ph3P=N)2S4N4 and (Ph3P=N)3S+S4N5−, have been isolated from the reaction of triphenylphosphine with S4N4; an X-ray structural determination of (Ph3P=N)2S4N4 shows it to consist of a 1,5-disubstituted S4N4 ring with the exocyclic substituents in an axial, equatorial configuration.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v79-518

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