KINETICS OF THE THERMAL DECOMPOSITION OF TETRAMETHYLTETRAZEN

Author:

Watson J. S.,Waring A. J.

Abstract

The kinetics of the thermal decomposition of tetramethyltetrazen (T.M.T.) have been studied in a static system at pressures up to 1.8 × 10−2 mm and temperatures between 125.5 and 147.5 °C by measuring the rate of production of nitrogen. The results show that the decomposition is first order in T.M.T. at the pressures used and give approximate values for the Arrhenius parameters.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Reference1 articles.

Cited by 8 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. MONOMETALLIC AND BIMETALLIC PT-BASED NANOPARTICLES AS TETRAMETHYLTETRAZENE (TMTZ) DECOMPOSITION CATALYSTS;International Journal of Energetic Materials and Chemical Propulsion;2018

2. Reaktionsgeschwindigkeiten;Eigenschaften der Materie in Ihren Aggregatzuständen;2013

3. Cage Effects in Dimethylaminyl Radical Formation;Journal of Macromolecular Science: Part A - Chemistry;1979-08

4. Reactivities of amino and aminium radicals: oxidative photoaddition of tetramethyl-2-tetrazene to olefins;Journal of the American Chemical Society;1978-04

5. A comparison of the heterolytic vs. homolytic cleavage of the nitrogen-chlorine bond;Journal of the American Chemical Society;1977-01

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