Abstract
The matrix elements of the polarizability anisotropy γ in the Raman spectra of diatomic molecules are investigated. These matrix elements are given by [Formula: see text] where Gνν′(m) is the rotational factor with m = [(J′(J′ + 1) − J(J + 1)]/2 and J′ − J = ±2. By using a nonconventional approach to the Rayleigh–Schrödinger perturbation theory the rotational factor can be written as Gνν′(m) = A0 + A1m + A2m2 where the coefficients A0, A1, and A2 are given by simple analytical expressions in terms of the integrals [Formula: see text] and [Formula: see text] where Y stands for Ψ(0) (the pure vibration wave function), or Ψ(0) (the first rotational perturbative correction to Ψ(0), or Ψ(2) (the second correction). A numerical application is presented for the ground states of CO and H2 molecules. A comparison with a numerical and direct calculation of the rotational factor Gνν′(m) shows the accuracy of the present formalism.
Publisher
Canadian Science Publishing
Subject
General Physics and Astronomy
Cited by
25 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献