STUDIES IN THE WAGNER–MEERWEIN REARRANGEMENT: PART IV. DERIVATIVES OF BENZ[b]FLUORENE-Reference-Cited by-同舟云学术

STUDIES IN THE WAGNER–MEERWEIN REARRANGEMENT: PART IV. DERIVATIVES OF BENZ[b]FLUORENE

Published:1960-02-01 Issue:2 Volume:38 Page:240-243
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Anet F. A. L.,Bavin P. M. G.

Abstract

10-Methyl-10-benz[b]fluorenylmethyl tosylate gave mainly 5-methylbenz[a]anthracene on formolysis, but the related alcohol gave a mixture of the 5- and 6-methyl isomers by reaction with phosphorus pentoxide. Reaction of benz[b]fluorenone with excess diazomethane gave 5-methoxybenz[a]anthracene as the only isolable product. The alkylation of methyl benz[b]fluorene-10-carboxylate was studied.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v60-032

Reference10 articles.

1. Studies in the Wagner Rearrangement.1-3 IV. The Steric Effect of an Ortho Methyl Group

2. Studies in the Wagner Rearrangement.1,2,3 II. The Synthesis and Structure Determination of Benz[a]anthracene-5,6-C114

3. Studies in the Wagner Rearrangement.1-3 III. Chrysene-5,6-C114

4. Studies in the Wagner Rearrangement. VI. The Directive Effects of the Methyl and Methoxyl Groups1

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1. In Memoriam: The Life and Scientific Accomplishments of Frank A. L. Anet (1926–2024);Journal of Physical Organic Chemistry;2024-08-26

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3. SYNTHESIS OF SUBSTITUTED BENZ[A]ANTHRACENES;Journal of Synthetic Organic Chemistry, Japan;1978

4. The synthesis of phenanthrenes;Chemical Reviews;1976-10-01

5. 5,6-DIMETHYLBENZ[a]ANTHRACENE AND 5,6-DIMETHYLBENZO[c]PHENANTHRENE;Canadian Journal of Chemistry;1962-07-01