Pyridine, thiophosphine, and selenophosphine complexes of the phenylphosphine dication-Reference-Cited by-同舟云学术

Pyridine, thiophosphine, and selenophosphine complexes of the phenylphosphine dication

Published:2018-07 Issue:7 Volume:96 Page:689-693
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Sinclair Hannah¹,Suter Riccardo¹,Burford Neil¹,McDonald Robert²,Ferguson Michael J.²

Affiliation:

1. Department of Chemistry, University of Victoria, Victoria, BC V8W 3V6, Canada.

2. X-ray Crystallography Laboratory, Department of Chemistry, University of Alberta, Edmonton, AB T6G 2G2, Canada.

Abstract

Compounds of the generic formula [PhPL][OTf]2 with L = bipyridine (bipy) and 4,4′-di(tert-butyl)-2,2′-bipyridine (Bbipy) and [PhPL2][OTf]2 with L = 4-dimethylaminopyridine (dmap), tricyclohexyl-thiophosphine, and tricyclohexyl-selenophosphine have been prepared by the reaction of dichlorophenylphosphine with two equivalents of trimethylsilyl triflate and the respective ligand. The new complexes of the phenylphosphine dication with this variety of ligands expands the scope of coordination complexes involving phosphorus as an acceptor.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/cjc-2017-0596

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