Fe(NO3)3·9H2O-catalyzed aerobic oxidative deoximation of ketoximes and aldoximes under mild conditions-Reference-Cited by-同舟云学术

Fe(NO3)3·9H2O-catalyzed aerobic oxidative deoximation of ketoximes and aldoximes under mild conditions

Published:2018-08 Issue:8 Volume:96 Page:810-814
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Li Yongshu¹,Xu Nizhou¹²,Mei Guangyao³,Zhao Yun²,Zhao Yiyong²,Lyu Jinghui²,Zhang Guofu²,Ding Chengrong²

Affiliation:

1. College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou 310014.

2. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014.

3. Zhejiang Hongyan Pharmaceutical Co., Ltd., Taizhou 317016, People’s Republic of China.

Abstract

A mild, simple process for the effective aerobic oxidative deoximation of a wide range of ketoximes and aldoximes has been developed that utilizes Fe(NO3)3·9H2O as the single catalyst and molecular oxygen as the green oxidant. The environmentally benign protocol provides moderate to excellent yield and broad functional groups tolerance and is a valuable synthetic method for practical applications. According the relevant verification experiment, a plausible mechanism has been proposed.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/cjc-2017-0567

Reference60 articles.

1. aSandler, S. R.; Karo, W. Organic Functional Group Preparations, 2nd ed.; Academic Press: San Diego, 1989; Vol. 3;

2. Regioselective Synthesis of Functionalized Oxime Ethers

3. aGreene, T. W.; Wuts, P. G. M. Protective Groups in Organic Synthesis, 2nd ed.; Wiley: New York, 1991;

4. Greene's Protective Groups in Organic Synthesis

5. The Palladium Assisted Transfer Reduction of α, β-Unsaturated Nitroalkenes to Oximes Using Ammonium Formate

Cited by 13 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Polyaniline-supported tungsten-catalyzed oxidative deoximation reaction with high catalyst turnover number;Chinese Chemical Letters;2023-01

2. Photocatalytic aerobic oxidative deoximation reaction with degradable rhodamine B;Reaction Chemistry & Engineering;2023

3. Unified Total Syntheses of Benzenoid Cephalotane-Type Norditerpenoids: Cephanolides and Ceforalides;Journal of the American Chemical Society;2022-10-05

4. Catalytic Oxidative Cleavage of C(OH)-C Bonds in Lignin Model Compounds to Carboxylic Acids by Fe(NO3)3.9H2O/NaI/DMSO;Frontiers in Chemistry;2022-07-01

5. PhSe(O)OH/NHPI-catalyzed oxidative deoximation reaction using air as oxidant;Molecular Catalysis;2021-09