Fe(NO3)3·9H2O-catalyzed aerobic oxidative deoximation of ketoximes and aldoximes under mild conditions-Reference-Cited by-同舟云学术

Fe(NO3)3·9H2O-catalyzed aerobic oxidative deoximation of ketoximes and aldoximes under mild conditions

Published:2018-08 Issue:8 Volume:96 Page:810-814
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Li Yongshu¹,Xu Nizhou¹²,Mei Guangyao³,Zhao Yun²,Zhao Yiyong²,Lyu Jinghui²,Zhang Guofu²,Ding Chengrong²

Affiliation:

1. College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou 310014.

2. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014.

3. Zhejiang Hongyan Pharmaceutical Co., Ltd., Taizhou 317016, People’s Republic of China.

Abstract

A mild, simple process for the effective aerobic oxidative deoximation of a wide range of ketoximes and aldoximes has been developed that utilizes Fe(NO3)3·9H2O as the single catalyst and molecular oxygen as the green oxidant. The environmentally benign protocol provides moderate to excellent yield and broad functional groups tolerance and is a valuable synthetic method for practical applications. According the relevant verification experiment, a plausible mechanism has been proposed.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/cjc-2017-0567

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