Synthesis, characterization, and application of palladium complexes containing bis(aminophosphine) ligands

Author:

Jones Christina1,Timm Matthew1,Masuda Jason D.2,Xia Aibing1

Affiliation:

1. Department of Chemistry, Mount Saint Vincent University, Halifax, NS B3M 2J6, Canada.

2. Department of Chemistry, Saint Mary’s University, Halifax, NS B3H 3C3, Canada.

Abstract

Two palladium complexes containing bis(aminophosphine) ligands have been prepared and characterized. Their solid structures were determined by X-ray single crystal diffraction studies. They were successfully employed in the Suzuki coupling reactions of phenylboronic acid and various aryl chlorides.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Reference26 articles.

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2. Organotransition Metal Chemistry: From Bonding to Catalysis; Hartwig, J. F., Ed.; University Science Books: Sausalito, CA, 2010; pp. 34–35, 603–609, 759–763.

3. Phosphino-amine (PN) Ligands for Rapid Catalyst Discovery in Ruthenium-Catalyzed Hydrogen-Borrowing Alkylation of Anilines: A Proof of Principle

4. Reactivity of bis(organoamino)phosphanes with magnesium(ii) compounds

5. A Highly Selective Ethylene Tetramerization Catalyst

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