True Nuclear Magnetic Shielding Constants for Members of Isoelectronic Series with 3 to 10 Electrons

Abstract

True values of the nuclear magnetic shielding constants are evaluated from approximate Hartree–Fock values for members of isoelectronic series with 3 to 10 electrons after making estimates of corrections due to the correlation effect. It is found that the correlation corrections are quite small and in certain cases their values turn out to be negative.