Chiral bidentate N-heterocyclic carbene complexes of Rh and Pd-Reference-Cited by-同舟云学术

Chiral bidentate N-heterocyclic carbene complexes of Rh and Pd

Published:2004-12-01 Issue:12 Volume:82 Page:1781-1787
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Ren Li,Chen Austin C,Decken Andreas,Crudden Cathleen M

Abstract

The synthesis of a new chiral, bidentate oxazoline/imidazolidene carbene precursor is described. This species is reacted with various metal salts in the presence of a base to generate rhodium and palladium complexes, which are characterized spectroscopically and crystallographically.Key words: chiral N-heterocyclic carbene, rhodium, palladium, oxazolidine, asymmetric catalysis.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v04-165

Reference23 articles.

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5. An N-Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross-Coupling of Sterically Hindered Aryl Chlorides at Room Temperature

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