THE PARTIAL STRUCTURES OF ACONITINE AND ACONITOLINE

Author:

Mayer Hans,Marion Léo

Abstract

In aconitoline (C33H41O10N), the product of the oxidation of aconitine with chromic acid, the presence of an αβ-unsaturated carbonyl group has been confirmed. The determination of the basic strengths of aconitoline and its various hydrolytic and reduction products revealed a very strong influence of the carbonyl on the basicity of the alkaloid. It was concluded that the secondary hydroxyl that becomes oxidized must be located in close proximity to the nitrogen. Partial structures are suggested to represent both aconitine and aconitoline.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 16 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Determination ofAconitumAlkaloids in the Tubers ofAconitum japonicumusing Gas Chromatography/Selected Ion Monitoring;Planta Medica;1996-02

2. Chapter 3 Chemistry of the Diterpenoid Alkaloids;The Alkaloids: Chemistry and Pharmacology;1992

3. Alkaloids of Delphinium corumbosum;Chemistry of Natural Compounds;1973-07

4. THE ACONITE ALKALOIDS;The Tetracyclic Diterpenes;1968

5. THE STRUCTURE OF INDACONITINE;Canadian Journal of Chemistry;1964-12-01

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