Abstract
The molecular complexes of urea and even-numbered n-paraffins up to C28 undergo thermal decomposition below the melting point of urea at temperatures which increase with the n-paraffin chain length. The decomposition is endothermal and is accompanied by changes in crystal structure, appearance, and by loss of the n-paraffin. Based on the enthalpy change a mechanism for the decomposition process is proposed.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
71 articles.
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