Author:
Tung Tzu-Lin,Stone John A.
Abstract
Transient disulfide radical anions have been produced by flash photolysis. Cyclic anions decay only by second order reaction as opposed to the first order decay found for linear ones at low concentration. Linear disulfides, except oxidized penicillamine, increase the rate of decay of the cystine radical anion. The pH dependence of the reaction with cystine suggests that the disulfide radical anion is an electrophile.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
16 articles.
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