Author:
Chiang Y.,Kresge A. J.,Young C. I.
Abstract
Rates of hydrolysis of cis- and trans-β-phenylvinyl methyl ethers, cis- and trans-β-(p-nitrophenyl)vinyl methyl ethers, and cis- and trans-β-cyanovinyl ethyl ethers were measured in concentrated (10–55 wt%) aqueous perchloric acids. The results show that these cis and trans isomers do not interconvert under the hydrolysis reaction conditions, and that formation of the alkoxy carbonium ion intermediate in these reactions is therefore not reversible.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
39 articles.
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