The (5d10 + 5d96s) – 5d96p transitions in Tl IV, Pb V, and Bi VI

Abstract

The spectra of thallium, lead, and bismuth were photographed in the region 600–2000 Å using sliding spark and triggered spark sources. The (5d10 + 5d96s)–5d96p transitions in Tl IV, Pb V, and Bi VI were investigated. Earlier level values were revised and new lines were classified. Hyperfine structure splittings were observed for many lines in Tl IV and Bi VI. Least squares fitted calculations were done for each spectra. The deviations between the calculated and observed level values showed that parametric descriptions using only the spin-orbit magnetic interaction parameter to describe magnetic effects is not sufficient in the 5d-shell spectra.