A stereochemical investigation of substituted ethylene sulfites via 13C nuclear magnetic resonance-Reference-Cited by-同舟云学术

A stereochemical investigation of substituted ethylene sulfites via 13C nuclear magnetic resonance

Published:1976-05-01 Issue:9 Volume:54 Page:1428-1432
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Buchanan Gerald W.,Hellier Desmond G.

Abstract

13C nmr chemical shifts for ethylene sulfite and 17 derivatives are presented. From the magnitudes of the γ shifts and the tenets of conformational analysis, support is gained for the existence of twist-envelope conformations in solution. Pseudorotational paths are suggested which do not involve inversion at the sulfur atom.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v76-204

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