Tetraphosphinitoresorcinarene complexes A new structural form of a rhodium(I) diphosphine complex-Reference-Cited by-同舟云学术

Tetraphosphinitoresorcinarene complexes A new structural form of a rhodium(I) diphosphine complex

Published:2004-10-01 Issue:10 Volume:82 Page:1423-1427
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Eisler Dana J,Puddephatt Richard J

Abstract

Tetrakis(diphenylphosphinito)resorcinarene ligands are shown to react with [Rh2(µ-Cl)2(CO)4] to give tetrarhodium(I) complexes in which there are two dirhodium units, each having the unprecedented structure syn-[Rh2(µ-Cl)2(CO)2P2], P = phosphinite donor.Key words: rhodium, resorcinarene, tetraphosphinite, carbonyl.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v04-099

Reference6 articles.

1. Dinuclear bridged d8 metal complexes. V. Preparation and structure of [Rh(SR)(CO)2L]2 and [Rh(SR)(CO)L]2 complexes (L = tertiary phosphine; R = phenyl, tert-butyl)

2. p-tert-Butylcalix[4]arene Tetrakis(diphenylphosphinite) and Tetrakis(dimethylphosphinite) Acting as Phosphorus Binding Surfaces for Monometallic and Homo- and Heterodimetallic Fragments

3. Calixarene and resorcinarene ligands in transition metal chemistry

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