A novel fluorescent sensor based on 4-(diethylamino)-2-(hydroxy)-phenyl imine functionalized naphthalimide for highly selective and sensitive detection of CN– and Fe3+

Abstract

In this work, a novel sensor molecule HB1, based on a 4-(diethylamino)-2-(hydroxy)-phenyl imine functionalized naphthalimide derivative, was successfully designed and synthesized. Interestingly, the HB1 showed fluorescence identification ability for CN– in DMSO/H2O (8:2, v/v) solution. After addition of CN– into the HB1 solution, the fluorescence intensity of HB1 solution could be enhanced obviously. The anti-disturbance experiments demonstrated that other anions could not interfere in the detection of CN–. On the other hand, HB1 was capable of dual-channel (absorption and fluorescence) detection of Fe3+ in DMSO solution. With the addition of various metal ions into the HB1 solution, only Fe3+ induced the fluorescence emission of HB1 solution quenching and the colour change, and other metal ions could not interfere in the detection of Fe3+. The limits of detection (LODs) of HB1 for CN– and Fe3+ were 6.30 × 10−8 and 3.95 × 10−8 mol/L, respectively. Importantly, the real sample experiment was carried out by detecting CN– in bitter almonds. Additionally, ion test strips based on HB1 were fabricated, which could act as convenient and efficient test kits for detecting CN– and Fe3+.