Electron spin resonance study of γ-irradiated tetraethylammonium iodide
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Published:1968-08-15
Issue:16
Volume:46
Page:2749-2752
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ISSN:0008-4042
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Container-title:Canadian Journal of Chemistry
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language:en
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Short-container-title:Can. J. Chem.
Author:
Fabes L.,Wan J. K. S.
Abstract
γ-Irradiation of polycrystalline tetraethylammonium iodide at 77°K leads to the breaking of a C—C bond and the primary radicals ĊH3 and [Formula: see text] were detected by electron spin resonance. The methyl radicals were found to disappear readily at 120°K. In the range of 263–273°K a secondary reaction between [Formula: see text] and the parent ion [Formula: see text] was observed; the resulting secondary radical [Formula: see text] was found to be stable up to 373°K.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
3 articles.
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1. Electron Spin Resonance Study ofγ-Irradiated Morpholinium Hexafluorophosphate;Spectroscopy Letters;1969-04
2. Part 1;Atoms, Inorganic Radicals, and Radicals in Metal Complexes
3. Review articles, 63Cr1 - 70Sm1;Atoms, Inorganic Radicals, and Radicals in Metal Complexes