New complexes of the hydronium ion with crown ethers: synthesis and vibrational spectra

Author:

Chénevert Robert,Rodrigue André,Beauchesne Pierre,Savoie Rodrigue

Abstract

The charged-component complexes H3O+18-crown-6.CF3SO3, H3O+18-crown-6.SbF6, and (H3O+18-crown-6)2•PtCl62− have been isolated and studied by infrared and Raman spectroscopy, along with the previously reported H3O+18-crown-6C1O4 and H3O+18-crown-6PF6 adducts. Also synthesized were the corresponding derivatives with BF4 and PtCl62− anions, using dicyclohexano-18-crown-6 as the host for the hydronium ion.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

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