Author:
Drake John E.,Khasrou Layla N.,Mislankar Anil G.,Ratnani Raju
Abstract
Dimethyltellurium alkylene dithiophosphates of the type [Formula: see text] where G = —CMe2CMe2—, —CHMeCHMe—, —CH2CMe2CH2—, and —CH2CEt2CH2—, have been synthesized in 80–90% yields by reaction of the corresponding sodium or ammonium salts of the appropriate dithiophosphoric acids with dimethyltellurium dichloride in toluene. Me2Te[S2P(OPh)2]2 was also prepared in a similar fashion. The compounds have been characterised by elemental analyses and 1H, 13C, 31P, and 125Te NMR, infrared and Raman spectroscopy. The crystal structures of [Formula: see text] and [Formula: see text] were determined. [Formula: see text]1, crystallizes in space group P21/c (No. 14) with the cell parameters a = 12.707(3) Å, b = 11.482(2) Å, c = 16.782(2) Å, β = 98.00(1)°, V = 2424(1) Å3, Z = 4, R = 0.0399, Rw = 0.0343. [Formula: see text]4, crystallizes in space group [Formula: see text] (No. 2) with the cell parameters a = 12.580(3) Å, b = 13.313(3) Å, c = 8.206(1) Å, α = 91.28(2)°, β = 104.94(2)°, γ = 78.52(2)°, V = 1301(1) Å3, Z = 2, R = 0.0364, Rw = 0.0295. The immediate environment about tellurium in both molecules is that of the saw-horse structure typical of tellurium(IV) compounds with the two methyl groups equatorial and one sulfur atom from each dithiophosphate group occupying the axial positions. The consideration of the second sulfur atom as part of the coordinating sphere is discussed in terms of a modification of Pauling's approach to partial bond orders. The 1H NMR spectra suggest that these dithiophosphates may be fluxional in solution and/or that there is rapid exchange of the sulfur atoms.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
31 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献