Author:
Perkier Richard E.,Mcglinchey Michael J.
Abstract
The 500 MHz 1H and 125 MHz 13C spectra of ergosteryl and 7-dehydrocholesteryl acetate were recorded in C6D6 and CDCl3 and assigned using two-dimensional NMR techniques. It is shown that incorporation of an Fe(CO)3 or a Rh(acac) moiety onto the ring B diene system affects the chemical shifts of neighbouring protons and carbons. These changes are discussed in terms of the anisotropic properties of the organometallic fragments.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
9 articles.
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