Author:
Gilbert A. S.,Bernstein H. J.
Abstract
The equilibrium constant Kp has been obtained for the complex [Formula: see text] over a range of temperatures between 22 and 132 °C by monitoring the integrated intensity of the Raman scattered band from unassociated DCl in a mixture with dimethyl ether. By applying the relation In KP = −ΔH/RT + ΔS/R the quantities ΔH, ΔG, and ΔS have been evaluated.Broad νCl–H and νCl–D complex bands have been observed and are found to be polarized.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
9 articles.
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