Rh(I)-catalyzed cleavage of unactivated CO bonds Carbonylative rearrangement reactions of allenyl ethers to 2-carboalkoxy-1,3-dienes-Reference-Cited by-同舟云学术

Rh(I)-catalyzed cleavage of unactivated CO bonds Carbonylative rearrangement reactions of allenyl ethers to 2-carboalkoxy-1,3-dienes

Published:2005-06-01 Issue:6-7 Volume:83 Page:838-842
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Wender Paul A,Deschamps Nicole M,Sun Robert

Abstract

The initial examples of a Rh(I)-catalyzed carbonylative rearrangement reaction of allenyl ethers are described. The key reaction proceeds under remarkably mild conditions to provide good to excellent yields of 2-carboalkoxy-1,3-dienes.Key words: carbonylative rearrangement, C-O cleavage, σ bond activation, rhodium catalysis, allenyl ethers.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v05-085

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