Synergistic effect of co-reactant promotes one-step oxidation of cyclohexane into adipic acid catalyzed by manganese porphyrins-Reference-Cited by-同舟云学术

Synergistic effect of co-reactant promotes one-step oxidation of cyclohexane into adipic acid catalyzed by manganese porphyrins

Published:2015-07 Issue:7 Volume:93 Page:696-701
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Li Hui¹,She Yuanbin¹²,Fu Haiyan³,Cao Meijuan¹,Wang Jing⁴,Wang Tao¹

Affiliation:

1. Institute of Green Chemistry & Fine Chemical, College of Environmental & Energy Engineering, Beijing University of Technology, Beijing 100124, PR China.

2. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, PR China.

3. School of Pharmaceutical Sciences, South-Central University for Nationalities, Wuhan, Hubei 430074, PR China.

4. Huizhou Research Institute of Sun Yat-sen University, Huizhou, Guangdong 516081, PR China.

Abstract

The synergistic effect of cyclohexane and cyclohexanone promoted synthesis of adipic acid catalyzed by [MnIIIT(p-Cl)PP]Cl with cyclohexane and cyclohexanone as co-reactants. The results showed that the conversions of cyclohexane and cyclohexanone were significantly enhanced because of the cyclohexanone synergistic effect, and the higher selectivity to adipic acid was obtained with dioxygen as an oxidant. The studies indicated that the co-oxidation of cyclohexane and cyclohexanone was influenced by the initial molar ratio of cyclohexanone and cyclohexane, catalyst structure, catalyst concentrations, and reaction conditions. The preliminary mechanism of the co-oxidation reaction of cyclohexane and cyclohexanone using [MnIIIT(p-Cl)PP]Cl as the catalyst was proposed.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/cjc-2014-0515

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