Author:
Lubeigt X.,Flies F.,Bourgeois M. J.,Montaudon E.,Maillard B.
Abstract
Homolytic decomposition induced by addition of dichloromethyl radicals to β- and γ-unsaturated peroxides having a substituent on the chain linking the unsaturation and the peroxide function was studied. The stereochemistry of the heterocycles produced was determined by I3C NMR and the stereoselectivity of intramolecular homolytic substitution on the peroxidic bond discussed. Key words: unsaturated peroxides, homolytic intramolecular substitutions, radical additions, oxygenated heterocycles.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
8 articles.
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