THE THEORY OF CURRENT DISTRIBUTION AND POTENTIAL PROFILE AT AN ELECTRODE OF SIGNIFICANT OHMIC RESISTANCE

Author:

Conway B. E.,Gileadi E.,Oswin H. G.

Abstract

The problem of current distribution at an electrode of linear geometry having a significant ohmic resistance is examined for conditions where the ohmic potential drop along the electrode material is of the same order of magnitude as the metal–solution potential difference. This problem is of practical significance in primary and secondary cells at high current drains and in certain types of fuel cell electrodes. The current distribution and metal–solution potential profiles are calculated as limiting cases of a general theory. The true and apparent current–potential relations are compared theoretically.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

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